Photo-Induced Linkage Isomerism of Transition Metal Nitrosyl and Dinitrogen Complexes Studied by Photocrystallographic Techniques
نویسندگان
چکیده
منابع مشابه
Photoinduced linkage isomers of transition-metal nitrosyl compounds and related complexes.
The seminal discovery of light-induced changes in transition-metal nitrosyl complexes in the late 1970s and their identification as metastable linkage isomers almost 20 years after the initial discoveries have in recent years motivated a plethora of experimental and theoretical studies. They have raised the question of whether the linkage isomers play a role in the many crucial biological proce...
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Low temperature, single crystal photocrystallographic studies have been carried out on four square planar Group 10 complexes [Ni(PEt(3))(2)(NO(2))(2)] 1, [Pd(PPh(3))(2)(NO(2))(2)] 2, [Pd(AsPh(3))(2)(NO(2))(2)] 3 and [Pt(PPh(3))(2)(NO(2))(2)] 4, in which the two nitro groups adopt the trans configuration. Irradiation with UV light, at 100 K, of single crystals of complexes 1-3 photoisomerise fro...
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Transition Metal Complexes with Sulfur Ligands, LXIX* Chromium and Tungsten Nitrosyl Complexes with Sulfur Dominated Coordination Spheres: [C r(N O )/S 4')]v(* = \ , y = 2 \x = 2 ,y = 1), (NR4)2[W(NO)2('S2')2] (R = Me, «-Bu), [W(L)(NO)('S4')] (L = NO, NPM e3, N PEt3) and [//-0{W (N 0)('s7)}2] ('S2'2= 1.2-Benzenedithiolate(2-);'S4'2= 1.2-Bis(2-mercaptophenylthio)ethane(2-)); Syntheses, Propertie...
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ژورنال
عنوان ژورنال: Tetrahedron
سال: 2000
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(00)00503-2